Hi IanL
Does this mean the thermostat is shot/broken already? I agree with you on the aspect of the aircon getting warm. Its probably due to the rising temperature of the engine making the compressor work twice harder.
dindo
Go take a look under the hood - you're looking for the a/c condensor and the radiator - they're usually at the very front of the engine compartment, and usually the a/c condensor is in front of the radiator.
Now - the air flow is through the condensor and then through the radiator - it's very important that you understand this - because it means that a hot radiator does not have as much impact on the condenser as a hot condensor has on the radiator.
To make a long story short ...
Hot day = more heat energy in the passenger compartment to be removed = higher condensor temperatures.
Heavy traffic = reduced vehicle speed = reduced air flow through the condensor = reduced ability to dissipate the additional heat = hotter air coming off the condensor and onto the radiator.
Eventually the a/c just cannot remove any more heat from the passenger compartment because the condensor cannot get rid of it fast enough and the passenger compartment will start to heat up.
As this is happening - the radiator is being faced with a double whammy in the form of a reduced air flow due to the reduced vehicle speed PLUS the air being at a higher temperature due to the air conditioning load, the radiator cannot dissipate the engine heat fast enough so the engine temperature will start to climb.
Shutting off the a/c removes the additional heat that the condensor is trying to dump into the air, which allows the air reaching the radiator to be "less hot", allowing the radiator to do a better job of dissipating the engine heat.