yes, colder air is "better" (google and wikipedia can explain why).
IMO, get a thermometer, and measure the Intake Air Temperature (aka IAT). A cheapo outside thermometer can help indicate if FOR YOUR DRIVING SITUATION the IAT/ underhood air temp being sucked in is excessive compared to the ambient air.
Hint, some BBQ thermometers have a way to "probe" under the hood while displaying the temp remotely

You could also get a real resistance based IAT and monitor it via a meter.
And of course if you have a ODB based vehicle (with an IAT), "there's an app for that".
For example, on a 70* day cruising around at say 25-30 MPH, I'd be surprised if the underhood/IAT temps are more that 80*-90*.
But, get on a LA freeway in bumper-to-bumper (e.g. 5MPH) with it 90* outside, your underhood/IAT temps are likely to be 200*.
Note: in the LA freeway example, a hood scoop aint going to help much! An auxillary fan tho might help blow away some of the heat buildup more efficiently!